ASTM D4815-15b
Standard Test Method for Determination of MTBE, ETBE, TAME, DIPE, tertiary-Amyl Alcohol and C1 to C4 Alcohols in Gasoline by Gas Chromatography

Standard No.

ASTM D4815-15b

Release Date

2015

Published By

American Society for Testing and Materials (ASTM)

Status

Be replaced

Replace By

ASTM D4815-15b(2019)

Latest

ASTM D4815-22

Scope

5.1 Ethers, alcohols, and other oxygenates can be added to gasoline to increase octane number and to reduce emissions. Type and concentration of various oxygenates are specified and regulated to ensure acceptable commercial gasoline quality. Drivability, vapor pressure, phase separation, exhaust, and evaporative emissions are some of the concerns associated with oxygenated fuels.

5.2 This test method is applicable to both quality control in the production of gasoline and for the determination of deliberate or extraneous oxygenate additions or contamination.

1.1 This test method covers the determination of ethers and alcohols in gasolines by gas chromatography. Specific compounds determined are methyl tert-butylether (MTBE), ethyl tert-butylether (ETBE), tert-amylmethylether (TAME), diisopropylether (DIPE), methanol, ethanol, isopropanol, n-propanol, isobutanol, tert-butanol, sec -butanol, n-butanol, and tert-pentanol (tert-amylalcohol).

1.2 Individual ethers are determined from 0.208201;mass8201;% to 20.0 mass8201;%. Individual alcohols are determined from 0.208201;mass8201;% to 12.0 mass8201;%. Equations used to convert to mass8201;% oxygen and to volume8201;% of individual compounds are provided. At concentrations <0.20 mass8201;%, it is possible that hydrocarbons may interfere with several ethers and alcohols. The reporting limit of 0.20 mass8201;% was tested for gasolines containing a maximum of 10 volume8201;% olefins. It may be possible that for gasolines containing >10 volume8201;% olefins, the interference may be >0.20 mass8201;%. Annex A1 gives a chromatogram showing the interference observed with a gasoline containing 10 volume8201;% olefins.

1.3 This test method includes a relative bias correlation for ethanol in spark-ignition engine fuels for the U.S. EPA regulations reporting based on Practice D6708 accuracy assessment between Test Method D4815 and Test Method D5599 as a possible Test Method D4815 alternative to Test Method D5599. The Practice D6708 derived correlation equation is only applicable for ethanol in fuels in the concentration range from 2.28 % to 14.42 % by mass as measured by Test Method D4815. The applicable Test Method D5599 range for ethanol is from 2.16 % to14.39 % by mass as reported by Test Method D5599.

ASTM D4815-15b Referenced Document

• ASTM D1298 Standard Test Method for Density, Relative Density (Specific Gravity), or API Gravity of Crude Petroleum and Liquid Petroleum Products by Hydrometer Method
• ASTM D1744 Standard Test Method for Determination of Water in Liquid Petroleum Products by Karl Fischer Reagent
• ASTM D3606 Standard Test Method for Determination of Benzene and Toluene in Finished Motor and Aviation Gasoline by Gas Chromatography
• ASTM D4052 Standard Test Method for Density and Relative Density of Liquids by Digital Density Meter
• ASTM D4057 Standard Practice for Manual Sampling of Petroleum and Petroleum Products
• ASTM D4307 Standard Practice for Preparation of Liquid Blends for Use as Analytical Standards
• ASTM D4420 Standard Test Method for Determination of Aromatics in Finished Gasoline by Gas Chromatography)
• ASTM D5599 Standard Test Method for Determination of Oxygenates in Gasoline by Gas Chromatography and Oxygen Selective Flame Ionization Detection
• ASTM D6708 Standard Practice for Statistical Assessment and Improvement of Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material

ASTM D4815-15b history

• 2022 ASTM D4815-22 Standard Test Method for Determination of MTBE, ETBE, TAME, DIPE, tertiary-Amyl Alcohol and C1 to C4 Alcohols in Gasoline by Gas Chromatography
• 2019 ASTM D4815-15b(2019) Standard Test Method for Determination of MTBE, ETBE, TAME, DIPE, tertiary-Amyl Alcohol and C1 to C4 Alcohols in Gasoline by Gas Chromatography
• 2015 ASTM D4815-15b Standard Test Method for Determination of MTBE, ETBE, TAME, DIPE, tertiary-Amyl Alcohol and C1 to C4 Alcohols in Gasoline by Gas Chromatography
• 2015 ASTM D4815-15a Standard Test Method for Determination of MTBE, ETBE, TAME, DIPE, tertiary-Amyl Alcohol and C1 to C4 Alcohols in Gasoline by Gas Chromatography
• 2015 ASTM D4815-15 Standard Test Method for Determination of MTBE, ETBE, TAME, DIPE, tertiary-Amyl Alcohol and C1 to C4 Alcohols in Gasoline by Gas Chromatography
• 2013 ASTM D4815-13 Standard Test Method for Determination of MTBE, ETBE, TAME, DIPE, tertiary-Amyl Alcohol and C1 to C4 Alcohols in Gasoline by Gas Chromatography
• 2009 ASTM D4815-09 Standard Test Method for Determination of MTBE, ETBE, TAME, DIPE, tertiary-Amyl Alcohol and C₁ to C₄ Alcohols in Gasoline by Gas Chromatography
• 2004 ASTM D4815-04 Standard Test Method for Determination of MTBE, ETBE, TAME, DIPE, tertiary-Amyl Alcohol and C₁ to C₄ Alcohols in Gasoline by Gas Chromatography
• 2003 ASTM D4815-03 Standard Test Method for Determination of MTBE, ETBE, TAME, DIPE, tertiary-Amyl Alcohol and C₁ to C₄ Alcohols in Gasoline by Gas Chromatography
• 1999 ASTM D4815-99e1 Standard Test Method for Determination of MTBE, ETBE, TAME, DIPE, tertiary-Amyl Alcohol and C₁ to C₄ Alcohols in Gasoline by Gas Chromatography
• 1999 ASTM D4815-99 Standard Test Method for Determination of MTBE, ETBE, TAME, DIPE, tertiary-Amyl Alcohol and C₁ to C₄ Alcohols in Gasoline by Gas Chromatography