5.2 The breakthrough detection time, standardized breakthrough time, permeation rate, and cumulative permeation are key measures of the effectiveness of a clothing material as a barrier to the test chemical. Such information is used in the comparison of clothing materials during the process of selecting clothing for protection from hazardous chemicals. Long breakthrough detection times, long standardized breakthrough detection times, low amounts of cumulative permeation, and low permeation rates are characteristics of better barriers.
5.3 The sensitivity of the test method in detecting low permeation rates or amounts of the test chemical that permeate is determined by the combination of the analytical technique and collection system selected, and the ratio of material specimen area to collection medium volume or flow rate.
5.3.1 The analytical technique employed should be capable of measuring the concentration of the test chemical in the collection medium at, or below, levels consistent with the standardized breakthrough time value specified in 3.1.13 and at, or above, the steady-state permeation rate.
5.3.2 Often permeation tests will require measurement of the test chemical over several orders of magnitude in concentration, requiring adjustments in either the sample collection volume or concentration/dilution, or the analytical instrument settings over the course of the test.
5.3.3 Higher ratios of material specimen area to collection medium volume or flow rate permit earlier detection of breakthrough and detection of lower permeation rates and levels of cumulative permeation because higher concentrations of the test chemical in the collection medium will develop in a given ti...........
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