ASTM C1030-10
Standard Test Method for Determination of Plutonium Isotopic Composition by Gamma-Ray Spectrometry

Standard No.

ASTM C1030-10

Release Date

2010

Published By

American Society for Testing and Materials (ASTM)

Status

Be replaced

Replace By

ASTM C1030-10(2018)

Latest

ASTM C1030-10(2018)

Scope

The determination of plutonium isotopic composition by gamma-ray spectrometry is a nondestructive technique and when used with other nondestructive techniques, such as calorimetry (Test Method C1458) or neutron counting (Test Methods C1207, C1316, C1493, and C1500), can provide a wholly nondestructive plutonium assay necessary for material accountancy and safeguards needs.

Because gamma-ray spectrometry systems are typically automated, the routine use of the test method is fast, reliable, and is not labor intensive. The test method is nondestructive, requires no sample preparation, and does not create waste disposal problems.

This test method assumes that all plutonium in the measured item has the same isotopic distribution, often called isotopic homogeneity (see 7.2.4 and 7.2.5).

The ²⁴²Pu abundance is not measured by this test method and must be estimated from isotopic correlation techniques, stream averages, historical information, or other measurement techniques.

Americium-241 is a daughter product of ²⁴¹Pu. The ²⁴¹Am/²³⁹Pu atom ratio can also be determined by means of this test method (assuming a homogeneous isotopic distribution of plutonium and ²⁴¹Am). The determination of the ²⁴¹Am/²³⁹Pu atom ratio is necessary for the correct interpretation of a calorimetric heat measurement.

The isotopic composition of a given batch or item of plutonium is an attribute of that item and, once determined, can be used in subsequent inventory measurements to verify the identity of an item within the measurement uncertainties.

The method can also measure the ratio of other gamma-emitting isotopes to plutonium assuming they have the same spatial distribution as the plutonium in the item. Some of these “other” gamma-emitting isotopes include isotopes of uranium, neptunium, curium, cesium, and other fission products. The same methods of this standard can be used to measure the isotopic composition of uranium in items containing only uranium (3, 4, 5, 6).

1.1 This test method is applicable to the determination of isotopic abundances in isotopically homogeneous plutonium-bearing materials. This test method may be applicable to other plutonium-bearing materials, some of which may require modifications to the described test method.

1.2 The procedure is applicable to items containing plutonium masses ranging from a few tens of milligrams up to the maximum plutonium mass allowed by criticality limits.

1.3 Measurable gamma ray emissions from plutonium cover the energy range from approximately 30 keV to above 800 keV. K-X-ray emissions from plutonium and its daughters are found in the region around 100 keV. This test method has been applied to all portions of this broad spectrum of emissions.

1.4 The isotopic abundance of the ²⁴²Pu isotope is not directly determined because it has no useful gamma-ray signature. Isotopic correlation techniques may be used to estimate its relative abundance Refs (1) and (2).

1.5 This test method has been demonstrated in routine use for isotopic abundances ranging from 99 to <50 % ²³⁹Pu. This test method has also been employed for isotopic ab......

ASTM C1030-10 Referenced Document

• ANSI N15.36 American National Standard for Methods of Nuclear Material Control - Measurement Control Program - Nondestructive Assay Measurement Control and Assurance
• ASTM C1207 Standard Test Method for Nondestructive Assay of Plutonium in Scrap and Waste by Passive Neutron Coincidence Counting
• ASTM C1316 Standard Test Method for Nondestructive Assay of Nuclear Material in Scrap and Waste by Passive-Active Neutron Counting Using a 252 Cf Shuffler
• ASTM C1458 Standard Test Method for Nondestructive Assay of Plutonium, Tritium and&x2009;²⁴¹Am by Calorimetric Assay*， 2024-04-19 Update
• ASTM C1493 Standard Test Method for Non-Destructive Assay of Nuclear Material in Waste by Passive and Active Neutron Counting Using a Differential Die-Away System
• ASTM C1500 Standard Test Method for Nondestructive Assay of Plutonium by Passive Neutron Multiplicity Counting
• ASTM C697 Standard Test Methods for Chemical, Mass Spectrometric, and Spectrochemical Analysis of Nuclear-Grade Plutonium Dioxide Powders and Pellets
• ASTM C698 Standard Test Methods for Chemical, Mass Spectrometric, and Spectrochemical Analysis of Nuclear-Grade Mixed Oxides ((U, Pu)O₂)
• ASTM C982 Standard Guide for Selecting Components for Energy-Dispersive X-Ray Fluorescence (XRF) Systems
• ASTM E181 Standard Test Methods for Detector Calibration and Analysis of Radionuclides
• ASTM E267 Standard Test Method for Uranium and Plutonium Concentrations and Isotopic Abundances

ASTM C1030-10 history

• 2018 ASTM C1030-10(2018) Standard Test Method for Determination of Plutonium Isotopic Composition by Gamma-Ray Spectrometry
• 2010 ASTM C1030-10 Standard Test Method for Determination of Plutonium Isotopic Composition by Gamma-Ray Spectrometry
• 2003 ASTM C1030-03 Standard Test Method for Determination of Plutonium Isotopic Composition by Gamma-Ray Spectrometry
• 1995 ASTM C1030-95(2001) Standard Test Method for Determination of Plutonium Isotopic Composition by Gamma-Ray Spectrometry
• 1995 ASTM C1030-95 Standard Test Method for Determination of Plutonium Isotopic Composition by Gamma-Ray Spectrometry