EN 1948-1:2006 Stationary source emissions - Determination of the mass concentration of PCDDs/PCDFs and dioxin-like PCBs - Part 1: Sampling of PCDDs/PCDFs
This European Standard has been developed to measure PCDD/PCDF concentrations at about
0,1 ng I-TEQ/m3 in stationary source emissions.
This European Standard specifies both method validation and a framework of quality control requirements
which shall be fulfilled by any PCDD/PCDF sampling.
The user has the possibility to choose between three different methods:
⎯ "filter/condenser method"
⎯ "dilution method"
⎯ "cooled probe method"
Each sampling method is illustrated by some sampling systems described in detail in Annex B as examples of
proven procedures.
During comparison measurements of the three sampling methods on municipal waste incinerators at the level
of about 0,1 ng I-TEQ/m3 these methods have been deemed comparable within the expected range of
uncertainty. Validation trials were performed on the flue gas of municipal waste incinerators at the level of
about 0,1 ng I-TEQ/m3 and a dust loading of from 1 mg/m3 to 15 mg/m3. Although this European Standard is
primarily developed and validated for gaseous streams emitted by waste incinerators, the practical experience
shows that it can be applied for wide concentration ranges and various emission sources.
The procedure described in the three parts of EN 1948 specifies requirements which shall be met in order to
measure the 17 congeners necessary to calculate the total I-TEQ (see Table A.1).
Besides the determination of PCDDs/PCDFs the described measurement methods are suitable for
determination of other low-volatile substances, e.g. of dioxin-like PCBs (details for sampling and analyses see
CEN/TS 1948-4), although no validated performance characteristics are available yet.
EN 1948-1:2006 Referenced Document
EN 13284-1 Stationary source emissions - Determination of low range mass concentration of dust - Part 1: Manual gravimetric method*, 2017-11-01 Update
EN 14789 Stationary source emissions - Determination of volume concentration of oxygen - Standard reference method: Paramagnetism*, 2017-01-01 Update
EN 14790 Stationary source emissions - Determination of the water vapour in ducts - Standard reference method*, 2017-01-01 Update
EN 1948-2:2006 Stationary source emissions - Determination of the mass concentration of PCDDs/PCDFs and dioxin-like PCBs - Part 2: Extraction and clean-up of PCDDs/PCDFs
EN 1948-3:2006 Stationary source emissions - Determination of the mass concentration of PCDDs/PCDFs and dioxin-like PCBs - Part 3: Identification and quantification of PCDDs/PCDFs
EN ISO/IEC 17025 General requirements for the competence of testing and calibration laboratories*, 2017-12-01 Update
EN 1948-1:2006 history
2006EN 1948-1:2006 Stationary source emissions - Determination of the mass concentration of PCDDs/PCDFs and dioxin-like PCBs - Part 1: Sampling of PCDDs/PCDFs
1996EN 1948-1:1996 Stationary Source Emissions - Determination of the Mass Concentration of PCDDs/PCDFs - Part 1: Sampling