1.1 This specification covers nominally anhydrous denatured fuel ethanol intended to be blended with unleaded or leaded gasolines at 1 % to 15 % by volume for use as automotive spark-ignition engine fuel covered by Specification D4814 as well as other fuel applications or specifications involving ethanol. The significance of this specification is shown in Appendix X1.
1.2 Jurisdictions may vary in their regulatory requirements for the allowable or prohibited types of denaturants, chemical composition of the denaturant or concentration of denaturant needed to denature the ethanol. The user is advised to check with the national and regional regulatory agencies where the ethanol is denatured and used.
1.2.1 Specific regulatory requirements for denatured fuel ethanol and acceptable denaturants from various jurisdictions are given in Appendixes for information.
1.3 The values stated in SI units are to be regarded as standard.
1.3.1 Exception—Values given in parentheses are provided for information only. Non-SI units are shown in the Appendix if they are in a direct quotation from government regulations. In most cases, U.S. federal regulations specify non-SI units.
1.4 The following safety hazards caveat pertains only to the method modification in
8.7 of this specification: This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
ASTM D4806-20 Referenced Document
ASTM D1298 Standard Test Method for Density, Relative Density (Specific Gravity), or API Gravity of Crude Petroleum and Liquid Petroleum Products by Hydrometer Method
ASTM D1613 Standard Test Method for Acidity in Volatile Solvents and Chemical Intermediates Used in Paint, Varnish, Lacquer, and Related Products
ASTM D1688 Standard Test Methods for Copper in Water
ASTM D2622 Standard Test Method for Sulfur in Petroleum Products by Wavelength Dispersive X-ray Fluorescence Spectrometry
ASTM D3120 Standard Test Method for Trace Quantities of Sulfur in Light Liquid Petroleum Hydrocarbons by Oxidative Microcoulometry
ASTM D381 Standard Test Method for Existent Gum in Fuels by Jet Evaporation
ASTM D4052 Standard Test Method for Density and Relative Density of Liquids by Digital Density Meter
ASTM D4057 Standard Practice for Manual Sampling of Petroleum and Petroleum Products
ASTM D4175 Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
ASTM D4177 Standard Practice for Automatic Sampling of Petroleum and Petroleum Products
ASTM D4306 Standard Practice for Aviation Fuel Sample Containers for Tests Affected by Trace Contamination
ASTM D4814 Standard Specification for Automotive Spark-Ignition Engine Fuel
ASTM D5453 Standard Test Method for Determination of Total Sulfur in Light Hydrocarbons, Spark Ignition Engine Fuel, Diesel Engine Fuel, and Engine Oil by Ultraviolet Fluorescence
ASTM D5501 Standard Test Method for Determination of Ethanol Content of Denatured Fuel Ethanol by Gas Chromatography
ASTM D5580 Standard Test Method for Determination of Benzene, Toluene, Ethylbenzene, p/m-Xylene, o-Xylene, C9 and Heavier Aromatics, and Total Aromat
ASTM D5854 Standard Practice for Mixing and Handling of Liquid Samples of Petroleum and Petroleum Products
ASTM D6423 Standard Test Method for Determination of pHe of Ethanol, Denatured Fuel Ethanol, and Fuel Ethanol (Ed75-Ed85)
ASTM D6550 Standard Test Method for Determination of Olefin Content of Gasolines by Supercritical-Fluid Chromatography
ASTM D7039 Standard Test Method for Sulfur in Gasoline, Diesel Fuel, Jet Fuel, Kerosine, Biodiesel, Biodiesel Blends, and Gasoline-Ethanol Blends by Monochromatic Wavelength Dispersive X-ray Fluorescence Spectro
ASTM D7318 Standard Test Method for Existent Inorganic Sulfate in Ethanol by Potentiometric Titration
ASTM D7319 Standard Test Method for Determination of Existent and Potential Sulfate and Inorganic Chloride in Fuel Ethanol and Butanol by Direct Injection Suppressed Ion Chromatography
ASTM D7328 Standard Test Method for Determination of Existent and Potential Inorganic Sulfate and Total Inorganic Chloride in Fuel Ethanol by Ion Chromatography Using Aqueous Sample Injection
ASTM D7347 Standard Test Method for Determination of Olefin Content in Denatured Ethanol by Supercritical Fluid Chromatography
ASTM D7576 Standard Test Method for Determination of Benzene and Total Aromatics in Denatured Fuel Ethanol by Gas Chromatography
ASTM D7757 Standard Test Method for Silicon in Gasoline and Related Products by Monochromatic Wavelength Dispersive X-ray Fluorescence Spectrometry
ASTM D7795 Standard Test Method for Acidity in Ethanol and Ethanol Blends by Titration
ASTM D7923 Standard Test Method for Water in Ethanol and Hydrocarbon Blends by Karl Fischer Titration
ASTM D86 Standard Test Method for Distillation of Petroleum Products
ASTM E1064 Standard Test Method for Water in Organic Liquids by Coulometric Karl Fischer Titration
ASTM E203 Standard Test Method for Water Using Volumetric Karl Fischer Titration
ASTM E29 Standard Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
ASTM E300 Standard Practice for Sampling Industrial Chemicals
ASTM D4806-20 history
2021ASTM D4806-21a Standard Specification for Denatured Fuel Ethanol for Blending with Gasolines for Use as Automotive Spark-Ignition Engine Fuel
2021ASTM D4806-21 Standard Specification for Denatured Fuel Ethanol for Blending with Gasolines for Use as Automotive Spark-Ignition Engine Fuel
2020ASTM D4806-20 Standard Specification for Denatured Fuel Ethanol for Blending with Gasolines for Use as Automotive Spark-Ignition Engine Fuel
2019ASTM D4806-19a Standard Specification for Denatured Fuel Ethanol for Blending with Gasolines for Use as Automotive Spark-Ignition Engine Fuel
2019ASTM D4806-19 Standard Specification for Denatured Fuel Ethanol for Blending with Gasolines for Use as Automotive Spark-Ignition Engine Fuel
2018ASTM D4806-18a Standard Specification for Denatured Fuel Ethanol for Blending with Gasolines for Use as Automotive Spark-Ignition Engine Fuel
2018ASTM D4806-18 Standard Specification for Denatured Fuel Ethanol for Blending with Gasolines for Use as Automotive Spark-Ignition Engine Fuel
2017ASTM D4806-17 Standard Specification for Denatured Fuel Ethanol for Blending with Gasolines for Use as Automotive Spark-Ignition Engine Fuel
2016ASTM D4806-16a Standard Specification for Denatured Fuel Ethanol for Blending with Gasolines for Use as Automotive Spark-Ignition Engine Fuel
2016ASTM D4806-16 Standard Specification for Denatured Fuel Ethanol for Blending with Gasolines for Use as Automotive Spark-Ignition Engine Fuel
2015ASTM D4806-15 Standard Specification for Denatured Fuel Ethanol for Blending with Gasolines for Use as Automotive Spark-Ignition Engine Fuel
2014ASTM D4806-14 Standard Specification for Denatured Fuel Ethanol for Blending with Gasolines for Use as Automotive Spark-Ignition Engine Fuel
2013ASTM D4806-13a Standard Specification for Denatured Fuel Ethanol for Blending with Gasolines for Use as Automotive Spark-Ignition Engine Fuel
2013ASTM D4806-13 Standard Specification for Denatured Fuel Ethanol for Blending with Gasolines for Use as Automotive Spark-Ignition Engine Fuel
2012ASTM D4806-12 Standard Specification for Denatured Fuel Ethanol for Blending with Gasolines for Use as Automotive Spark-Ignition Engine Fuel
2011ASTM D4806-11a Standard Specification for Denatured Fuel Ethanol for Blending with Gasolines for Use as Automotive Spark-Ignition Engine Fuel
2011ASTM D4806-11 Standard Specification for Denatured Fuel Ethanol for Blending with Gasolines for Use as Automotive Spark-Ignition Engine Fuel
2010ASTM D4806-10b Standard Specification for Denatured Fuel Ethanol for Blending with Gasolines for Use as Automotive Spark-Ignition Engine Fuel
2010ASTM D4806-10a Standard Specification for Denatured Fuel Ethanol for Blending with Gasolines for Use as Automotive Spark-Ignition Engine Fuel
2010ASTM D4806-10 Standard Specification for Denatured Fuel Ethanol for Blending with Gasolines for Use as Automotive Spark-Ignition Engine Fuel
2009ASTM D4806-09 Standard Specification for Denatured Fuel Ethanol for Blending with Gasolines for Use as Automotive Spark-Ignition Engine Fuel
2008ASTM D4806-08a Standard Specification for Denatured Fuel Ethanol for Blending with Gasolines for Use as Automotive Spark-Ignition Engine Fuel
2008ASTM D4806-08 Standard Specification for Denatured Fuel Ethanol for Blending with Gasolines for Use as Automotive Spark-Ignition Engine Fuel
2007ASTM D4806-07a Standard Specification for Denatured Fuel Ethanol for Blending with Gasolines for Use as Automotive Spark-Ignition Engine Fuel
2007ASTM D4806-07 Standard Specification for Denatured Fuel Ethanol for Blending with Gasolines for Use as Automotive Spark-Ignition Engine Fuel
2006ASTM D4806-06c Standard Specification for Denatured Fuel Ethanol for Blending with Gasolines for Use as Automotive Spark-Ignition Engine Fuel
2006ASTM D4806-06b Standard Specification for Denatured Fuel Ethanol for Blending with Gasolines for Use as Automotive Spark-Ignition Engine Fuel
2006ASTM D4806-06a Standard Specification for Denatured Fuel Ethanol for Blending with Gasolines for Use as Automotive Spark-Ignition Engine Fuel
2006ASTM D4806-06 Standard Specification for Denatured Fuel Ethanol for Blending with Gasolines for Use as Automotive Spark-Ignition Engine Fuel
2004ASTM D4806-04a Standard Specification for Denatured Fuel Ethanol for Blending with Gasolines for Use as Automotive Spark-Ignition Engine Fuel
2004ASTM D4806-04 Standard Specification for Denatured Fuel Ethanol for Blending with Gasolines for Use as Automotive Spark-Ignition Engine Fuel
2003ASTM D4806-03 Standard Specification for Denatured Fuel Ethanol for Blending with Gasolines for Use as Automotive Spark-Ignition Engine Fuel
2002ASTM D4806-02 Standard Specification for Denatured Fuel Ethanol for Blending with Gasolines for Use as Automotive Spark-Ignition Engine Fuel
2001ASTM D4806-01a Standard Specification for Denatured Fuel Ethanol for Blending with Gasolines for Use as Automotive Spark-Ignition Engine Fuel
2001ASTM D4806-01 Standard Specification for Denatured Fuel Ethanol for Blending with Gasolines for Use as Automotive Spark-Ignition Engine Fuel
1999ASTM D4806-99 Standard Specification for Denatured Fuel Ethanol for Blending with Gasolines for Use as Automotive Spark-Ignition Engine Fuel