ASTM C1672-23
Standard Test Method for Determination of the Uranium, Plutonium or Americium Isotopic Composition or Concentration by the Total Evaporation Method Using a Thermal Ionization Mass Spectrometer

Standard No.

ASTM C1672-23

Release Date

2024

Published By

American Society for Testing and Materials (ASTM)  US  /  ASTM

Latest

ASTM C1672-23

Scope

1.1  This method describes the determination of the isotopic composition, or the concentration, or both, of uranium, plutonium, and americium as nitrate solutions by the total evaporation method using a thermal ionization mass spectrometer (TIMS) instrument. Purified uranium, plutonium, or americium nitrate solutions are deposited onto a metal filament and placed in the mass spectrometer. Under computer control, ion currents are generated by heating of the filament(s). The ion currents are continually measured until the whole deposited solution sample is exhausted. The measured ion currents are integrated over the course of the measurement and normalized to a reference isotope ion current to yield isotope ratios.

1.2  In principle, the total evaporation method should yield isotope ratios that do not require mass bias correction. In practice, samples may require this bias correction. Compared to the conventional TIMS method described in Test Method C1625 , the total evaporation method is approximately two times faster, improves precision of the isotope ratio measurements by a factor of two to four, and utilizes smaller sample sizes. Compared to the C1625 method, the total evaporation method provides “major” isotope ratios 235U/238U, 240Pu/239Pu, and 241Am/243Am with improved accuracy.

1.3  The total evaporation method is prone to biases in the “minor” isotope ratios (233U/238U, 234U/238U, and 236U/238U ratios for uranium materials and 238Pu/239Pu, 241Pu/239Pu, 242Pu/239Pu, and 244Pu/239Pu ratios for plutonium materials) due to peak tailing from adjacent major isotopes. The magnitude of the absolute bias is dependent on measurement and instrumental characteristics. The relative bias, however, depends on the relative isotopic abundances of the sample. The use of an electron multiplier equipped with an energy filter may eliminate or diminish peak tailing effects. Measurement of the abundance sensitivity of the instrument may be used to ensure that such biases are negligible, or may be used to bias correct the minor isotope ratios.

1.4  The values stated in SI units are to be regarded as standard. When non-SI units are provided in parentheses, they are for information only.

1.5  This standard may involve the use of hazardous materials and equipment. This standard does not purport to address all the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and to determine the applicability of regulatory limitations prior to use.

1.6  This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ASTM C1672-23 Referenced Document

• ASTM C1068 Standard Guide for Qualification of Measurement Methods by a Laboratory Within the Nuclear Industry
• ASTM C1156 Standard Guide for Establishing Calibration for a Measurement Method Used to Analyze Nuclear Fuel Cycle Materials
• ASTM C1168 Standard Practice for Preparation and Dissolution of Plutonium Materials for Analysis
• ASTM C1347 Standard Practice for Preparation and Dissolution of Uranium Materials for Analysis
• ASTM C1415 Standard Test Method for ²³⁸Pu Isotopic Abundance by Alpha Spectrometry
• ASTM C1625 Standard Test Method for Uranium and Plutonium Concentrations and Isotopic Abundances by Thermal Ionization Mass Spectrometry*， 2024-10-01 Update
• ASTM C1816 Standard Practice for The Ion Exchange Separation of Small Volume Samples Containing Uranium, Americium, and Plutonium Prior to Isotopic Abundance and Content Analysis*， 2024-07-01 Update
• ASTM C1832 Standard Test Method for Determination of Uranium Isotopic Composition by Modified Total Evaporation (MTE) Method Using Thermal Ionization Mass Spectrometer*， 2025-11-01 Update
• ASTM C753 Standard Specification for Nuclear-Grade, Sinterable Uranium Dioxide Powder
• ASTM C757 Standard Specification for Nuclear-Grade Plutonium Dioxide Powder, Sinterable
• ASTM C776 Standard Specification for Sintered Uranium Dioxide Pellets for Light Water Reactors
• ASTM C787 Standard Specification for Uranium Hexafluoride for Enrichment
• ASTM C833 Standard Specification for Sintered (Uranium-Plutonium) Dioxide Pellets
• ASTM C859 Standard Terminology Relating to Nuclear Materials
• ASTM C967 Standard Specification for Uranium Ore Concentrate
• ASTM C996 Standard Specification for Uranium Hexafluoride Enriched to Less Than 5% 235U1

ASTM C1672-23 history

• 2024 ASTM C1672-23 Standard Test Method for Determination of the Uranium, Plutonium or Americium Isotopic Composition or Concentration by the Total Evaporation Method Using a Thermal Ionization Mass Spectrometer
• 2017 ASTM C1672-17 Standard Test Method for Determination of Uranium or Plutonium Isotopic Composition or Concentration by the Total Evaporation Method Using a Thermal Ionization Mass Spectrometer
• 2007 ASTM C1672-07(2014) Standard Test Method for Determination of Uranium or Plutonium Isotopic Composition or Concentration by the Total Evaporation Method Using a Thermal Ionization Mass Spectrometer
• 2007 ASTM C1672-07 Standard Test Method for Determination of Uranium or Plutonium Isotopic Composition or Concentration by the Total Evaporation Method Using a Thermal Ionization Mass Spectrometer

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